https://youtu.be/rtFX92dZE_w?t=1873 This link will take you to the explanation of /f and incident angle
The shift and speed (/f ) are correlated. The /f determines the maximum incidence angle, this combined with your scope type (obstruction or no) determines the distribution of angles that make it to the sensor. the lower your /f, the more shift you need to allow all the photons to transmit. For a refractor the photons come in from 0-maximum angle. With a SCT or hyperstar, the central obstruction blocks the low incidence angle photons, so you just need to worry about transmitting from some moderate angle to the maximum angle, you need to shift the filter to allow the desired incident angles to be transmitted at the wavelength of interest.
As I was figuring this stuff out, I made this video which gets into some of the topics looking at a refactor and SCT
https://youtu.be/RSw6vDhSrIU if you get me your email, I can send you the excel file from this (
https://youtu.be/IudhLAjqD8E) and you can play with it. - you can find my address on my youtube -> About page.
For me, if I want to learn something, I need to teach it to someone else, so you get my youtube videos like this.
Also, if you are playing with spectroscopy, you should learn how to do non-linear fits. If you post a .csv or .xls file of that peak data I can build a solver that would fit the curve - much like how pHD2 guiding can provide sub-pixel guiding accuracy, you can get a much better measure of the center of your peak if you fit the line to a guassian.
There is a way to do this in excel using the 'solver' plug in.
if you want to really dive in - the open source program fityk is really powerful (but has a learning curve)
https://fityk.nieto.pl/