Hi,
i am sure marcel could offer better insight regarding this topic ;) but ill try my best to explain how discoveries are done
There are lots of sky survey's which were prepared for studying and finding new objects and we take help of these like DSS POSS II survey, or IPHAS halpha survey , the discoveries that are made have gone through extensive examination of these survey and amateur data, we search for specific isolated region which contains a hot star/White dwarf. The region should emit Halpha/OIII or both and should have a prominent shape size to decide about the object.
when we find such objects we quickly check if it has been discovered before or not by using research papers, SIMBAD and Hash if this object does not show up in any of these then its unknown
There are lots of other creteria that needs to be fullfilled before we submit for a new discovery
and when it gets fullfilled we submit it and later the spectrum is obtained and then we proceed to imaging the objects using professional instruments or amateur astrophotographers
currently we have found many many potential candidates which could be important discoveries
the famous STDR guys have found more than 140 New objects using amateur and professional data
in the end, finding new objects is not an easy job and requires thousands of hrs of work i am sure marcel can relate

.. so if you are willing to find new objects make sure you are really dedicated to it hehe

thanks
Utkarsh