Hi,
Each mount has a periodic error. This represents small bumps and other impefections in the gear which result in a predictable movement with every cycle.
As an example think that one particular tooth in the worm wheel is a little longer than the others. Every time that tooth touches the worm screw, the increased resistance makes things slower and tracking lags by a few arcsec. Always the same few arcsec.
The total error in tracking that occurs during a period (a full rotation of the system) is called the periodic error, PE.
The duration T of the period itself is the other important number.
The rate e= PE/T gives you how much your mount will err per second. If you track for t seconds and et>your resolution in arcsecs, you will have star trails.
Example:
period = 500 secondsperiodic
error = 10 arcsec
resolution = 2.96 arcsec per pixel (Canon EOS 40D with 300mm lens).
Your error rate in the example is 0.02 arcsec/pixel so you should be able to achieve about 150 seconds without star trails, assuming of course no wind, perfect balancing, polar alignment and total weight well within your mount's payload capacity (all of those things can cause star trails and are more likely to cause them with longer exposures).
This is an average value, mind. It could be that your worm is almost perfect for the first 80% of it's cycle while having many anomalies in the remaining 20%. In that case you would be able to achieve up to 400 seconds when in the "good" part of the cycles and not even 2 seconds during the "bad" part. But the average is what you are able to do, well, on average.
So to answer your question, you need to look up your mount's worm period and periodic error. I believe for a SA the numbers are close to 50 and 500 respectively so approximately 30-45 seconds is the best you can expect at 300mm on average. This matches my experience at the slightly larger 360mm, where 30 seconds is good while 45 seconds gives about 50% keepers.
Cheers,
Dimitris